Faculty Members

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Designated Assistant Professor ASAHARA Haruyasu


Year of birth Gender Male
Affiliation School of Environmental Science and Engineering
Research Institute
Research Center for Materials Science and Engineering, Research Institute
Job titles
Personal web site

Areas of specialization
Laboratory/research office
Current reseach topics
Educational background 2010: Doctor
Professional background 2016-: 
2013-: 
2011-: 
2010-: 
2010-: 
Licenses
Academic societies

Courses  * Courses provided in English are shown with (E) mark

Undergraduate school ▼

Graduate school ▼

Research activities

Research papers ▼

  1. Authors: Sho Hirai, ASAHARA Haruyasu, NISHIWAKI Nagatoshi
    Title: Acid Promoted Dimerization of α-Amino-α,β-unsaturated Amides Affording Bis(functionalized) Pyrrolinones
    Journal: Tetrahedron Letters, Vol. 57, pp. 5896-5898
    Year: 2016
  2. Authors: Le Thi Song, Toshiki Fujimoto, ASAHARA Haruyasu, NISHIWAKI Nagatoshi
    Title: Synthesis of 6-Substituted 2-Phenacylpyridines from 2-(Phenylethynyl)pyridine via Isoxazolo[2,3-a]pyridinium Salt
    Journal: Organic & Biomolecular Chemistry, Vol. 14, pp. 10674-10682
    Year: 2016
  3. Authors: ASAHARA Haruyasu, Kanami Inoue, TANI Shinki, UMEZU Kazuto, NISHIWAKI Nagatoshi
    Title: Direct Synthesis of N-Acyl-N,O-hemiacetals via Nucleophilic Addition of Unactivated Amides and Their O-Acetylation: Access to α,α-Difunctionalized N-Acylimines
    Journal: Advances Synthesis & Catalysis, Vol. 358, pp. 2817-2828
    Year: 2016
  4. Authors: Le Thi Song, Chisa Yasuoka, ASAHARA Haruyasu, NISHIWAKI Nagatoshi
    Title: Dual Behavior of Iodine Species in Condensation of Anilines and Vinyl Ethers Affording 2-Methylquinolines
    Journal: Molecules, Vol. 21, No. 827, pp. 1-11
    Year: 2016
  5. Authors: NAKAIKE Yumi , ASAHARA Haruyasu, NISHIWAKI Nagatoshi
    Title: Construction of Push-Pull Systems Using β-Formyl-β-nitroenamine
    Journal: Russian Chemical Bulletin, International Edition, p. in press
    Year: 2016
  6. Authors: Sho Hirai, ASAHARA Haruyasu, NISHIWAKI Nagatoshi
    Title: Chemoselective Amination of β-Keto Amides
    Journal: Current Organic Chemistry, Vol. 20, pp. 2911-2916
    Year: 2016
  7. Authors: Hao Feiyue, ASAHARA Haruyasu, NISHIWAKI Nagatoshi
    Title: A Direct and Vicinal Functionalization of the 1-Methyl-2-quinolone Framework: 4-Alkoxylation and 3-Chlorination
    Journal: Organic & Biomolecular Chemistry, Vol. 14, pp. 5128-5135
    Year: 2016
  8. Authors: ASAHARA Haruyasu, Ayaka Awane, Kengo Muragishi, SUGIMOTO Ryuichi, SAIGO, Kazuhiko, NISHIWAKI Nagatoshi
    Title: Investigation of a Green Oligomer of an Indolizine
    Journal: ARKIVOC, No. vi, pp. 259-273
    Year: 2016
  9. Authors: ASAHARA Haruyasu, Mai Hamada, Yumi Nakaike, NISHIWAKI Nagatoshi
    Title: Construction of 3,5-Dinitrated 1,4-Dihydropyridines modifiable at 1,4-Positions by a Reaction of β-Formyl-β-nitroenamines with Aldehydes
    Journal: RSC Advances, Vol. 5, pp. 90778-90784
    Year: 2015
  10. Authors: Le Thi Song, ASAHARA Haruyasu, NISHIWAKI Nagatoshi
    Title: An Alternative Synthetic Approach to 3-Alkylated/Arylated 5-Nitropyridines
    Journal: The Journal of Organic Chemistry , Vol. 80, pp. 8856-8858
    Year: 2015
  11. Authors: NISHIWAKI, Nagatoshi, Sayaka Hamada, Tomoe Watanabe, HIRAO, Shotaro, SAWAYAMA, Jun, ASAHARA,Haruyasu, SAIGO, Kazuhiko, KAMATA, Toru, FUNABASHI, Masahiko
    Title: Development of a New Palladium Catalyst Supported on Phenolic Resin
    Journal: RSC Advances, Vol. 5, pp. 4463-4467
    Year: 2015
  12. Authors: ASAHARA Haruyasu, Keita Arikiyo, NISHIWAKI Nagatoshi
    Title: Development of Variously Functionalized Nitrile Oxide
    Journal: Beilstein Journal of Organic Chemistry, Vol. 11, pp. 1241-1245
    Year: 2015
  13. Authors: ASAHARA,Haruyasu, Asuka Kataoka, HIRAO, Shotaro, NISHIWAKI, Nagatoshi
    Title: Functionalization of a Pyridine Framework via Intramolecular Reissert-Henze Reaction of N-Carbamoyloxypyridinium Salt and Unexpected Insertion of Ethereal Solvents
    Journal: European Journal of Organic Chemistry, pp. 3994-3999
    Year: 2015
  14. Authors: ASAHARA,Haruyasu, Syota Takeda, SAIGO, Kazuhiko, NISHIWAKI, Nagatoshi
    Title: Synthesis of Diazabicyclo Compounds Possessing an α-Nitrolactam Framework
    Journal: Tetrahedron Letters, Vol. 56, pp. 2504-2507
    Year: 2015
  15. Authors: Le Thi Song, ASAHARA,Haruyasu, NISHIWAKI, Nagatoshi
    Title: Metal-Free Synthesis of 2-Alkenyl/Alkynyl-5-nitropyridines Using Three-Component Ring Transformation
    Journal: Chemistry Letters, Vol. 44, pp. 776-778
    Year: 2015
  16. Authors: Le Thi Song, ASAHARA,Haruyasu, NISHIWAKI, Nagatoshi
    Title: Tailor-made Synthesis of N,N,2,6-Tetrasubstituted 4-Nitroanilines by Three-Component Ring Transformation of Dinitropyridone
    Journal: European Journal of Organic Chemistry, pp. 1203-1206
    Year: 2015
  17. Authors: Wang, Pengyu, Tohriyama, Hiroko , Yokoyama, Kazuya, OHTANI, Masataka, ASAHARA,Haruyasu, KONISHI, Tomoya, NISHIWAKI, Nagatoshi, SHIMODA, Masahiko, YAMASHITA, Yoshiyuki, YOSHIKAWA, Hideki, KOBIRO, Kazuya
    Title: Smart Decoration of Mesoporous TiO2 Nanospheres with Noble Metal Alloy Nanoparticles into Core–Shell, Yolk–Core–Shell, and Surface-Dispersion Morphologies
    Journal: European Journal of Inorganic Chemistry, Vol. 2014, pp. 4254-4257, Wiley
    Year: 2014/08/15
  18. Authors: ASAHARA,Haruyasu, NISHIWAKI, Nagatoshi
    Title: Metal-Free α-Hydroxylation of α-Unsubstituted β-Oxoesters and β-Oxoamides
    Journal: The Journal of Organic Chemistry, Vol. 79, No. 23, pp. 11735-11739
    Year: 2014
  19. Authors: ASAHARA,Haruyasu
    Title: Kinetic Resolution of Primary Amines via Enantioselective N-Acylation with Acyl Chlorides in the Presence of Supramolecular Cyclodextrin Nanocapsules
    Journal: Tetrahedron, Vol. 70, No. 2, pp. 197-203
    Year: 2014
  20. Authors: NISHIWAKI, Nagatoshi, HIRAO, Shotaro, SAWAYAMA, Jun, ASAHARA,Haruyasu, SUGIMOTO,Ryuichi, KOBIRO, Kazuya, SAIGO, Kazuhiko
    Title: Synthesis of Vicinally Functionalized 1,4-Dihydropyridines and Diazabicycles via a Pseudo-Intramolecular Process
    Journal: Tetrahedron, Vol. 70, pp. 402-408
    Year: 2014
  21. Authors: Syou Hirai, ASAHARA,Haruyasu, HIRAO, Shotaro, SAWAYAMA, Jun, SUGIMOTO,Ryuichi, SAIGO, Kazuhiko, NISHIWAKI, Nagatoshi
    Title: An NMR Study on a Pseudo-Intramolecular Transacylation Reaction of an α-Aryl-β-keto Ester
    Journal: RSC Advances, Vol. 4, No. 10, pp. 4889-4892
    Year: 2014
  22. Authors: Le Thi Song, ASAHARA,Haruyasu, KOBIRO, Kazuya, SUGIMOTO,Ryuichi, SAIGO, Kazuhiko, NISHIWAKI, Nagatoshi
    Title: Synthesis of 2-Aryl-5-nitropyridines by Three Component Ring Transformation of 3,5-Dinitro-2-pyridone
    Journal: Asian Journal of Organic Chemistry , Vol. 3, No. 3, pp. 297-302, Wiley
    Year: 2014
  23. Authors: June Takaichi, Yuma Morimoto, Kei Ohkubo, Chizu Shimokawa, Takayuki Hojo, Seiji Mori, ASAHARA,Haruyasu, Hideki Sugimoto, Nobutaka Fujieda, NISHIWAKI, Nagatoshi, Shunichi Fukuzumi, Shinobu Itoh
    Title: Redox Chemistry of Nickel(II)-Complexes Supported by a Series of Non-innocent β-Diketiminate Ligands
    Journal: Inorganic Chemistry, Vol. 53, No. 12, pp. 6159-6169
    Year: 2014
  24. Authors: NISHIWAKI, Nagatoshi, Yasuyuki Mori, Erina Fukuoka, ASAHARA,Haruyasu, HIRAO, Shotaro, SAWAYAMA, Jun, SAIGO, Kazuhiko, KONISHI, Tomoya, SHIMODA, Masahiko
    Title: Facilitation of the Reduction of Pd(II) by the Glass Surface -Development of a Glass-Supported Palladium Catalyst-
    Journal: Chemical Physics Letters , Vol. 608, pp. 340-343
    Year: 2014
  25. Authors: ASAHARA,Haruyasu, Kyo Muto, NISHIWAKI, Nagatoshi
    Title: Safe Cyano(nitro)methylating Reagent -Michael Addition of Cyano-aci-nitroacetate Leading to δ-Functionalized α-Nitronitriles-
    Journal: Tetrahedron, Vol. 70, pp. 6522-6528
    Year: 2014
  26. Authors: ASAHARA,Haruyasu, Yuki Kuribayashi, Wang Pengyu, KOBIRO, Kazuya, NISHIWAKI, Nagatoshi
    Title: An Effect of Microwave Irradiation on Pd/SiC Catalyst for Prolonging the Catalytic Life
    Journal: Current Microwave Chemistry, Vol. 1, pp. 142-147
    Year: 2014
  27. Authors: LE Thi Song, ASAHARA,Haruyasu, NISHIWAKI, Nagatoshi
    Title: An Efficient Synthesis of Nitrated Cycloalka[b]pyridines
    Journal: Synthesis, pp. 2175-2178
    Year: 2014
  28. Authors: HIRAI, Sho, ASAHARA,Haruyasu, SUGIMOTO,Ryuichi, SAIGO, Kazuhiko, NISHIWAKI, Nagatoshi
    Title: Revisiting Dimerization of Acetoacetamide Leading to 4,6-Dimethyl -2-pyridone-5-carboxamide
    Journal: Journal of Oleo Science, Vol. 63, No. 9, pp. 939-942
    Year: 2014
  29. Authors: ASAHARA,Haruyasu
    Title: Unique Catalytic Effect of A Cyclodextrin Host on Photodimerization of Coumarin in Nonpolar Solvents
    Journal: Tetrahedron Lett., Vol. 54, No. 7, pp. 688-691
    Year: 2013
  30. Authors: ASAHARA,Haruyasu
    Title: Cyclodextrin host as a supramolecular catalyst in nonpolar solvents: stereoselective synthesis of (E)-3-alkylideneoxindoles
    Journal: Tetrahedron, Vol. 69, No. 45, pp. 9428-9433
    Year: 2013
  31. Authors: ASAHARA,Haruyasu
    Title: Chiral Recognition and Kinetic Resolution of Aromatic Amines via Supramolecular Chiral Nanocapsules in Nonpolar Solvents
    Journal: J. Am. Chem. Soc., Vol. 135, pp. 3371-3374
    Year: 2013
  32. Authors: CHEN Xin, KOBIRO, Kazuya, ASAHARA,Haruyasu, Kakiuchi, Kiyomi, SUGIMOTO,Ryuichi, SAIGO, Kazuhiko, NISHIWAKI, Nagatoshi
    Title: Reactive 2-Quinolones Dearomatized by Steric Repulsion between 1-Methyl and 8-Substited Groups
    Journal: Tetrahedron, Vol. 69, No. 23, pp. 4624-4630
    Year: 2013
  33. Authors: ASAHARA,Haruyasu
    Title: Versatile Domino Rearrangement of Diphenylhomobenzoquinone Epoxides Induced by CF3SO3H
    Journal: Eur. J. Org. Chem., Vol. 2012, No. 21, pp. 3916-3919
    Year: 2012
  34. Authors: ASAHARA,Haruyasu
    Title: 1-[2,2-Bis(phenylsulfonyl)ethenyl]-4- methoxybenzene
    Journal: Acta Cryst. E., Vol. E68, p. o470
    Year: 2012
  35. Authors: ASAHARA,Haruyasu
    Title: 2-(4-Methoxybenzylidene)-2H-1,3- benzodithiole 1,1,3,3-tetraoxide
    Journal: Acta Cryst. E., Vol. E68, p. o567
    Year: 2012
  36. Authors: ASAHARA,Haruyasu
    Title: Electrophilicities of Bissulfonyl Ethylenes
    Journal: Chem. Asian J., Vol. 7, pp. 3581-3584
    Year: 2012
  37. Authors: ASAHARA,Haruyasu
    Title: Regioselective Electrophilic Addition vs Epoxidation of mCPBA towards Anti-Bredt Olefin of Fulleroid
    Journal: Tetrahedron Lett., Vol. 53, pp. 3581-3584
    Year: 2012
  38. Authors: ASAHARA,Haruyasu
    Title: Thermal [2+2] Cycloaddition of Morpholinoenamines with C60 via a Single Electron Transfer
    Journal: Org. Lett., Vol. 13, pp. 4244-4247
    Year: 2011
  39. Authors: ASAHARA,Haruyasu
    Title: Kinetic Evidence for Dihapto (η2) π-Aryl Participation in Acid-Catalyzed Ring Opening of Diarylhomobenzoquinone Epoxides
    Journal: J. Org. Chem., Vol. 75, pp. 733-740
    Year: 2010
  40. Authors: ASAHARA,Haruyasu
    Title: Conformational Effects in Acid-Mediated Ring Opening of Epoxides: A Prominent Role of the Oxirane Walsh Orbital
    Journal: Org. Lett., Vol. 10, pp. 2413-2416
    Year: 2008
  41. Authors: ASAHARA,Haruyasu
    Title: Mechanistic Evidence for Remote π-Aryl Participation in Acid-Catalyzed Ring Opening of Homobenzoquinone Epoxides
    Journal: Chem. Commun., Vol. 15, pp. 1804-1806
    Year: 2008
  42. Authors: ASAHARA,Haruyasu
    Title: Acid-Catalyzed Rearrangement of Aryl-Substituted Homobenzo-quinone Epoxides
    Journal: Tetrahedron Lett., Vol. 9, pp. 3421-3424
    Year: 2007
  43. Authors: ASAHARA,Haruyasu
    Title: Two Conformers of 10,11-Dihydro-5H-dibenzo[a,d]cycloheptene Spiro-Linked with Homobenzoquinone Epoxide
    Journal: Acta Cryst. C., Vol. C62, pp. o136-o138
    Year: 2006
  44. Authors: ASAHARA,Haruyasu
    Title: Conformational Analysis in the Reversible Intramolecular [2+2] Photocycloaddition of Diphenylbicyclo[4.2.0]oct-3-ene-2,5-diones
    Journal: Tetrahedron Lett., Vol. 47, pp. 7881-7884
    Year: 2006
  45. Authors: ASAHARA,Haruyasu
    Title: Acid-Catalyzed Transannular Cyclization of 3aH-Cyclopentene[8]annulene-1,4-(5H,9aH)-diones and Some Proposed Mechanisms
    Journal:  J. Org. Chem., Vol. 70, pp. 8364-8371
    Year: 2005

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Published books ▼

  1. Carbamoylnitrile Oxide and Inverse Electron-Demand 1,3-Dipolar Cycloaddition in Methods and Application of Cycloaddition Reactions in Organic Syntheses Chapter 9, John Wiley & Sons, Inc., 2014, ISBN 978-1-118-299